Since 2022, Russia-Ukraine geopolitical conflicts have intensified, and global energy prices have risen sharply, with international natural gas prices hitting historic highs. As the most important transitional energy source in the transition from fossil energy to non-fossil energy, the share of natural gas in primary energy has increased from 14.6% in 1965 to 24.7% in 2020. The global gas price indices showed a unilateral downward trend from 2018, bottomed out in 2020, and remained low for a long time. However, since July 2020, the global gas prices have gradually fluctuated upward, and the impact of geopolitical events made the Dutch TTF gas price even hit record highs repeatedly.
An analyst of a securities company believes that the core catalyst of this round of global gas market lies in the lack of investment in upstream oil and gas resources caused by long-term low prices. Since 2020, although the epidemic has led to a decline in demand, the decline in supply has been faster, resulting in a large inventory consumption. In 2021, demand will recover faster than supply (the supply-side is less sensitive to prices, which will be reflected in investment).
As the world's two largest gas 3D printing metal powder are also expected to change significantly.
Metal 3D printing is a 3D printing technology that uses metal powder to directly print metal parts, also known as Selective Laser Melting (SLM).
In addition to good plasticity, 3D printed metal powders must also meet the requirements of small particle size, narrow particle size distribution, high sphericity, good fluidity and high bulk density.
The metal powders used in most 3D printers include stainless steel, aluminum alloy, cobalt-chromium alloy, copper alloy, titanium alloy and nickel alloy. Iron base alloy is the most important and largest metal material in engineering technology. It is widely used in the forming of complex structures and is widely used in aerospace, automobile, shipbuilding, machinery manufacturing and other industries.
The type of metal powder and the 3D printing process used determine the performance of the final product
Stainless steel powder
Relatively cheap metal printing materials, cost-effective, good corrosion resistance, high strength, can be quickly and efficiently small batch of complex industrial parts manufacturing.
Aluminium alloy powder
At present, aluminum alloys used in metal 3D printing mainly include AlSi12 and AlSi10Mg. Aluminosilicate 12 is a lightweight additive used to produce metal powders with good thermal properties. The combination of silicon and magnesium gives aluminum alloys higher strength and stiffness, making them suitable for thin walls and complex geometry, especially in applications with good thermal properties and low weight. Aluminum alloy is one of the most widely used non-ferrous metal structural materials in industry, its low density, high specific strength, close to or more than high quality steel, good plasticity. Research shows that aluminum alloy used for 3D printing can achieve compact parts, small structure, mechanical properties comparable to casting or even better than casting molding parts, and compared with traditional process parts, the mass can be reduced by 22%, but the cost can be reduced by 30%.
Cobalt chromium alloy powder
Due to its excellent wear resistance and corrosion resistance, metal 3D-printed cobalt-chromium alloy powder is commonly used to print all kinds of artificial joints and plastic surgery implants, and is also useful in the field of dentistry.
Copper alloy powder
With excellent thermal conductivity and electrical conductivity, copper with excellent thermal conductivity in thermal management applications can combine design degrees of freedom to produce complex internal structures and conformal cooling channels.
Titanium alloy powder
It is widely used in the aerospace field. The advantages of 3D printing can help optimize product design, such as replacing the original solid body with a complex and reasonable structure, so that the finished product has lower weight and better mechanical properties. This can not only reduce the cost, but also realize the lightweight production of each component.
Nickel alloy powder
The characteristics of oxidation and corrosion resistance of nickel alloy make it suitable for the harsh environment of high temperature and high pressure. When the nickel alloy is heated, the surface of the alloy will passivate a thick and stable oxide layer to protect the internal alloy from corrosion. Nickel alloys maintain good mechanical properties over a wide range of temperatures.
How Can Powdered Materials be Used For 3D Printing?
High energy laser beams are then controlled by 3D model data to locally melt the metal matrix while sintering the solidified powder metal material and automatically stack it in layers to generate solid parts with dense geometry.
How to Produce 3D Printing Metal Powder?
The four most widely used methods for producing metal powders are solid-state reduction, electrolysis, chemical and atomization.
Most manufacturers use electrolysis and reduction methods to produce elemental metal powders. But they are not suitable for making alloy powders.
The atomization method can be used to produce alloy powder.
Electrolysis is another method used to produce powdered metals. By choosing the right electrolyte composition, temperature, concentration, and current density, different metals can be deposited as spongy or powdered. This can then be washed, dried, reduced, annealed and crushed. This method is used to produce very high purity metal powder. Because of its high energy requirements, it is basically used for highly conductive copper powder.
Atomization method refers to the mechanical method to pulverize the molten metal into particles smaller than 150μm. According to the classification of crushing metal melt, atomization method includes the second flow atomization method, centrifugal atomization, ultrasonic atomization, vacuum atomization and so on. These atomization methods have their own characteristics and have been successfully applied in industrial production. Among them, the water-gas atomization method has the advantages of simple production equipment and process, low energy consumption, large batch, etc., and has become the main industrial production method of metal powder.
Performance Requirements of Metal Powder For 3D Printing
Ceramic inclusions will significantly reduce the performance of the final product, and these inclusions generally have a high melting point, difficult to sinter forming, so the powder must be free of ceramic inclusions. In addition, oxygen and nitrogen content also need to be strictly controlled. At present, the powder preparation technology used in metal 3D printing is mainly by atomization method. The powder has a large specific surface area and is easy to oxidize. In aerospace and other special applications, customers have more stringent requirements on this index, such as the oxygen content of superalloy powder is 0.006%-0.018%, titanium alloy powder oxygen content is 0.007%-0.013%, stainless steel powder oxygen content is 0.010%-0.025%.
2. Powder fluidity and loose density
The fluidity of powder directly affects the uniformity of powder spreading and the stability of powder feeding. The fluidity is related to powder morphology, particle size distribution and bulk density. The larger the powder particles are, the more regular the particle shape is, and the smaller the proportion of very fine powder in particle size composition is, the better the fluidity is. The fluidity of powder increases with the increase of relative density and particle density. In addition, the adsorption of water and gas on the particle surface reduces the fluidity of powder.
3. Powder particle size distribution
Different 3D printing equipment and forming process have different requirements for powder particle size distribution. At present, the powder particle size range commonly used in metal 3D printing is 15-53μm(fine powder) and 53-105μm(coarse powder). The selection of metal powder particle size for 3D printing is mainly divided according to metal printers with different energy sources. Printers with laser as energy source are suitable for 15-53μm powder because of its fine focal spot and easy to melt fine powder As consumable material, powder replenishment method is layer-by-layer powder; The powder-laying printer with electron beam as energy source has a slightly coarse focal spot, which is more suitable for melting coarse powder. It is mainly suitable for using 53-105μm coarse powder. For coaxial powder feeder printers, powder with particle size of 105-150μm can be used as consumables.
4. Powder morphology
The morphology of powder is closely related to the preparation method of powder. Generally, when metal gas or molten liquid is transformed into powder, the shape of powder particles tends to be spherical, and when metal solid is transformed into powder, the powder particles are mostly irregular shape, and most of the powder prepared by aqueous solution electrolysis is dendritic. Generally speaking, the higher the sphericity, the better the fluidity of the powder particles.3D printing of metal powder requires sphericity above 98%, which makes it easier to lay and feed powder during printing.
3D Printing Metal Powder Supplier
Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and nanomaterials, including silicon powder, nitride powder, graphite powder, zinc sulfide, calcium nitride, 3D printing powder, etc.
If you are looking for high-quality 3D printing metal powder, please feel free to contact us and send an inquiry. ([email protected])
Due to the limited total amount of traditional energy, people have a huge demand for cleaner and greener new energy alternatives. Now, the emergence of graphene is unlocking the possibility of its application in the energy field, which can create a greener, more efficient, and sustainable future. Here Francesco Bonaccorso, Deputy Director of Innovation at the Graphene Flagship Program, explains how his researchers have developed a series of initiatives to bring graphene from the lab to the commercial market. Graphene has become a research hotspot for new materials in the 21st century. Graphene has been adopted by many industries, the most notable of which are healthcare and key material applications.
The development of graphene has brought huge fluctuations in the demand for 3D printing metal powder, and the demand for 3D printing metal powder will continue to grow in the future. You can contact us for the latest news on 3D printing metal powder.
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